Sabtu, 13 Mei 2017

Using English to Calculate



how you calculate stoichiometry?

for this question please read this one!

The word stoichiometry is originated from the Greek word stoicheion meaning elementary constituent, and metrin relates to measuring. Stoichiometry involves quantitative calculations of reactants and products in chemical reactions. It’s based on the law of conservation of mass where the total mass of reactants is equal to the total mass of the products. Stoichiometry is founded on the law of conservation of mass where the total mass of the reactants = total mass of the products.  The amount of product can easily be calculated if the amounts of the separate reactants are known.

                       CH4 + 2 O2 → CO2 + 2 H2O


Here, One molecule of methane (CH4) reacts with 2 molecules of Oxygen gas to achieve 2 molecules of CO2 and two molecules of water. The quantitative relationship here is measured by the Stoichiometry and also used to find out the amount of reactants that are yield in a given reaction.

Solved Examples 

Example 1  Ammonia reacts with solid copper oxide and releases nitrogen gas, solid copper and water vapour. Write this chemical reaction and balance the equation according to its stoichiometry.

Solution:   The above example can be written as
NH3 + CuO —> Cu + H2O + N2
Balanced equation based on its stoichiometry,
2NH3 + 3CuO —> 3Cu + 3H2O + N2

Example 2 Sulphur trioxide gas is released on combustion of iron pyrites(FeS2). Describe the chemical reaction and balance the equation based on stoichiometry of every compound.
Solution: The chemical reaction for the above example is
FeS2 + O2 —> Fe2O3 + SO3

Combustion compounds react with oxygen.
The balanced chemical equation based on its stoichiometry is

4FeS2 + 15O2 —> 2Fe2O3 + 8SO3

Stoichiometry Problems

When we carry out a reaction in either an industrial setting or a laboratory, it is easier to work with masses of substances than with the numbers of molecules or moles. The general method for converting from the mass of any reactant or product to the mass of any other reactant or product using a balanced chemical equation is outlined in and described in the following text.

Steps in Converting between Masses of Reactant and Product

  1. Convert the mass of one substance (substance A) to the corresponding number of moles using its molar mass.
  2. From the balanced chemical equation, obtain the number of moles of another substance (B) from the number of moles of substance A using the appropriate mole ratio (the ratio of their coefficients).
  3. Convert the number of moles of substance B to mass using its molar mass. It is important to remember that some species are in excess by virtue of the reaction conditions. For example, if a substance reacts with the oxygen in air, then oxygen is in obvious (but unstated) excess.
Converting amounts of substances to moles—and vice versa—is the key to all stoichiometry problems, whether the amounts are given in units of mass (grams or kilograms), weight (pounds or tons), or volume (liters or gallons).
Figure 1. A Flowchart for Stoichiometric Calculations Involving Pure Substances
The molar masses of the reactants and the products are used as conversion factors so that you can calculate the mass of product from the mass of reactant and vice versa.To illustrate this procedure, let’s return to the combustion of glucose. We saw earlier that glucose reacts with oxygen to produce carbon dioxide and water:
Equation 1.
C6H12O6(s) + 6O2(g) → 6CO2(g) + 6H2O(l)
Just before a chemistry exam, suppose a friend reminds you that glucose is the major fuel used by the human brain. You therefore decide to eat a candy bar to make sure that your brain doesn’t run out of energy during the exam (even though there is no direct evidence that consumption of candy bars improves performance on chemistry exams). If a typical 2 oz candy bar contains the equivalent of 45.3 g of glucose and the glucose is completely converted to carbon dioxide during the exam, how many grams of carbon dioxide will you produce and exhale into the exam room?
The initial step in solving a problem of this type must be to write the balanced chemical equation for the reaction. Inspection of shows that it is balanced as written, so we can proceed to the strategy outlined in , adapting it as follows:
1.      Use the molar mass of glucose (to one decimal place, 180.2 g/mol) to determine the number of moles of glucose in the candy bar:

2.      Use the molar mass of CO2 (44.010 g/mol) to calculate the mass of CO2 corresponding to 1.51 mol of CO2:

3       3. We can summarize these operations as follows:
Discrepancies between the two values are attributed to rounding errors resulting from using stepwise calculations in steps 1–3.

12 komentar:

  1. what the goal we learn stoichionetry?

    BalasHapus
    Balasan
    1. one of the goal is Applying In Charging Battery.

      Hapus
  2. Is there any evect of reactant in chemical reaction?

    BalasHapus
  3. Can you give me more example about stoikiometry in dayly life?

    BalasHapus
    Balasan
    1. Calorimeter
      boil water
      Capillarity in water
      Charging battery

      Hapus
  4. What is the different between gay lusac law and avogadro?

    BalasHapus
    Balasan
    1. This relationship between temperature and pressure is known as Gay-Lussac's law. It states that if the volume of a container is held constant as the temperature of a gas increases, the pressure inside the container will also increase. As with the other gas laws, this one can be represented in the form of an equation:

      P1/T1 = P2/T2
      Avogadro’s law, a statement that under the same conditions of temperature and pressure, equal volumes of different gases contain an equal number of molecules. This empirical relation can be derived from the kinetic theory of gases under the assumption of a perfect (ideal) gas. The law is approximately valid for real gases at sufficiently low pressures and high temperatures

      Hapus
  5. What the different Mass molecul relativ (Mr) and Mass?

    BalasHapus
    Balasan
    1. The molar mass of a compound tells you the mass of 1 mole of that substance. In other words, it tells you the number of grams per mole of a compound. The units for molar mass are, therefore, grams/mole.
      An atomic mass is unit less and defined as precisely 1/12 the mass of an atom of carbon-12 not in motion. The carbon-12 (C-12) atom has six protons and six neutrons in its nucleus and it's atomic mass is exactly 12 by definition

      Hapus
  6. On your blog there is said about quantitative calculations of reactants and products in chemical reactions based on mass conservation law. Can you explain about the law of mass conservation ???

    BalasHapus
  7. I often wonder how to find Ar. So give me an example to look for Ar if that is known is Mr.?

    BalasHapus

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